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LTC 275-2007 Normandy Shores Golf Course Pesticide ApplicationRFC;~I~F~7 2003 DEC I 0 PIS 2~ { Q ~ MIAMI BEACH ci~Y ~:~~~;~~s o~~-~ OFFICE OF THE CITY MANAGER NO. LTC # Z~s-ZOOS SETTER TO COMMISSION TO: Mayor Matti Herrera Bower and Members of the City Commission FROM: Jorge M. Gonzalez, City Manage . ,,~/ DATE: December 7, 2007 SUBJECT: Normandy Shores Golf Course Pesticide Application The purpose of this LTC is to provide the Mayor and City Commission with an update on the results of a Florida Department of Agriculture and Consumer Services investigation that was initiated as a result of an allegation of pesticide exposure, by a Normandy Shores neighborhood resident, during the on-going construction of the Normandy Shores Golf Course (NSGC). Following an Invitation-to-Bid (ITB) and contractor evaluation and selection process, construction of the NSGC was awarded to the top-ranked firm of QGS Development Inc., a contractor with extensive golf course construction experience. A construction notice to proceed was issued to QGS on May 17, 2007 and construction of the NSGC proceeded. The contractor's scope of work included: the eradication of existing turf using herbicide applications as defined on the architect's turf eradication plan; removal of invasive tree and shrub vegetation identified on the tree removal plan; removal of existing golf cart paths and installation of a new cart path; renovation of 18 tee complexes and practice range tee; renovation of 19 greens, including practice putting green; installation of various golf course drainage systems, including drainage wells and enlargement of lake areas for storage; installation of a new irrigation pump station, including pump house structure, and irrigation system; and sprigging of Paspalum grass for all areas where existing turf was eradicated. The investigation by the Florida Department of Agriculture was initiated on August 1, 2007 and the final report received by the Capital Improvement Projects Office the week of December 2, 2007. Following a thorough investigation, including sampling and testing, the final determination by the State agency was that no violations could be identified and the case was closed. Attached for reference are copies of the letter from the Florida Department of Agriculture's Environmental Manager, which is self-explanatory, and the accompanying Pesticide Analysis Report. Should you have any questions or need additional information, please do not hesitate to contact me. JMG /J Attac ment F:\CAPI\$all\CANO\NSGC Pesticide Application LTC.doc Florida Department of rhgriculture and Gansumer Services CHARI.FS H. BR(.)NS0~1, Gomrnissior7er The Capitol • 'Tallahassee, Fl.. 3~39~-0800 wWW.daacS.state.fl.US Please Respond to: Bureau of Compliance Monitoring 3125 Conner Boulevard, Bldg. 8, L-29 Tallahassee, >=L 32399-1650 (850} 4$8-5872 November 26, 2007 City of Miami Beach Attn: Mr. Humberto Cabanas 1700 Convention Center Drive Miami Beach, Florida 33139 Dear Mr. Cabanas: On August 1, 20307, the Department of Agriculture and Consumer Services {"Department"} initiated an investigation in response to a report from Ms. Rebecca Kohn, of an alleged pesticide exposure. The report indicated that the Normandy Shores Ga#f Course had applied a pesticide in which the active ingredient was believed to be 2, 4-D and that her family was having ill health effects from the exposure. During this investigation, addt#onal a#legations were received from Ms. Rebecca Kohn regarding pesticide activities at Normandy Shores Golf Course. Ms. Kohn a1#eged that the applicators did not wear required personal protective equipment, that landscape workers did na# wear personal protective equipment while working in the treated areas, that the pesticide tank was improperly stored, that the boom height on the application equipment was greater than specified by the lobe#, that there was no water available for decontamination, that the firm operated pesticide application equipment in a dangerous manner and that there was an overall decrease in wildlife activity in the immediate area. It was a#so alleged that applicators used the pesticide paraquat and that some of the product had sp##led by a trailer across the street from a children's playground leaving a blue residue. During the investigation, the Department documented the use of the following pesticides: "Fusilade ll Turf and Ornamental Herbicide," EPA Reg. No. 100-1084, Sample Number 080707 4088 01 01. 2. "Nufarm Credit Systemic Extra Herbicide," EPA Reg. No. ?1368-20, Sample Number 080?07 4088 0102. 3. "f~oundup Rro Herbicide,,, EPA Reg. No. 524-473, Sample Number 09060? 4105 0101. 4t~r, _.~'"' __--._- _ ...._. ` a~ Florida Ag~`eulture at~d F«rest Products X97 Rillicyr~ far Florida's Ec~:~r~orr~y° City of Miami Beach November 26, ~€?t}7 Page Two The pepartment also collected twenty-one physical samples, seventeen samples from the Kohn's property and four samples from Normandy Shores Golf Coarse. The enclosed Pesticide Analysis Reports regarding the samples from the Kohn's property indicate that no pesticides were detected. However, two of the samples taken from the Nom~iandy Shores Golf Course indicate the presence of glyphosate and arninomethyl phosphoric acid, the active ingredients in Nu#arm Credit Systemic E~ctra Herbicic and Roundup Pro Herbicide. It was detemained that the area in which the positive samples were collected was treated by Mr. Maurice S. Greenwood, Fame Manager and licensed applicator with Quality Turf, L.C., with Nufarm Credit Systemic Extra Herbicide, Roundup Pro Herbicide and Fusilade Il Turf and {lmamental Herbicide in preparation for the construction of a golf cart garage. Therefore, the allegation of pesticide drift could not be c.~onfirmed. ®uring the investigation, Mr. Greenwood indicated that some blue marker dye was spilled near the trailers, however, no pesticides were spilled. It was noted Chart Quality TurF, L.C. does not use any products containing paraquat and the analysis results of the eight vegetation samples d9d nOt indicate the presence of paraqua#. In addition, we wefe unable to Obtair4 medical records regarding the ill health effects suffered by members of the Kohn family that would indicate a direct causal effect from pesticide e sure. After a complete review of the case file regarding this investigation, no violations were identified and the cause cif the Kohn family's ill health effects was inconclusive. Enctosed, per your request, is a copy of the entire case file on compact. disk. The t~epartei~it appreciates your cooperation during the investigation. if you have any questions regarding this matter, please feel free to contact me at ~8~Ct) X88-58'2. Sincerely, CHARLES H. BRQNC3N ct~~iylSSic~NI~:R al= AGRICULTURE Craig ~ryant, Enaironrnental Manager Pesticide Compliance Section CTB1kaf Enclosures cc: Mr, Bruce A. Nicely Ms. Patty A. Lucas Mr. Neil D. Richmond Ms. 1/ivian Martinez Mr. Rafael A. Llorente File: Nom3andy Shores Golf Course Fite No.: 'lt}7-X27-t}3 K~il' & '1Q7-2~-41t3 KAI= State of Florida Department of Agriculture & Consumer Services ~~ Tallahassee, Florida Charles li. ~ransoa Commissioner PESTICIA~ ANAt..YSIS REPdRT Report Date: 9/14{Z00'~ I:..alror>zto~ sample r>y; rLa7aoa Customer Ib: BCM EPA Sample Number: a$3107~105-0112 Compliantt Fik Number: IU7-2~15~105 Compliance 1F'ik Name: Nortnand~~ Shores Gulf Course This sample was received by our 1a6: Sample Description: Sn~rb sample into a 8oz.glass container' from a n~indon- close to north east cornet of the house. located at tht north side of the house (back side ot'the house) .top left glass of the ~ indoa•. Dote Sample Taken: a8/31/07 Sabmit Dah: U9/a5/07 The attached report is for the sample referenced above. The sample was analyzed using standard FDACS testing procedures and quality analysis protocol .instrument calihration and quality control are within acceptable limits of precision and accuracy. A close review by our Quality Assurance Deprtrtment certifies that our strict quality assurance standards were observed ;!'his Inver .sheet is an integral part of the analytical report that follows. Pesticide Laboratory REPUR~' t~F A~V'~I.'YSIS To: Bureau ol'Complianct Monitoring 3125 Conner Boulevard. BId8 Tallahassee, Fl. 32399-1650 IEl'A Sample No; 483107--0105-01 l2 Sample Matrix: SWAB Report Date: 9llarz007 Date Received: 09/05/07 Date Collected: 08/31!07 Sample Description: Swab sample into a $oz.glass container from a window close to north east corner of the house, located at the north side of the house (back side of the house) ,top left glass of the window. This sample was analyzed by standard Pestioidt Laboratory, FDACS testing procedures. Ali results were validated against standard QA procedures. Ax~alytieal Results Ana Res^It Aoa Utilt Ana a MU)<. Gfier Gtyphosate & AMPA ~ 5wab by - ug - LC/Flaores Amino 1 'e acid Not debec~ted G sate Not detected Comments: See attached page for report qualifitr detmitions if applicable ~~ ~~ P.A. Lucas, Division ofAES Pbrida I]epartmeet of Agriculture and Consumer Services (850) 488-9375 `. ,:.~ ,. State of Florida Department of Agriculture 8~ Caasumer Services 'T'allahassee, Florida Chaves x. 8ror~son Commissioner PESTICIDE ANALYSIS ltl/PORT Report Date: 9/14/Z007 1L,aboratory Sample ID: P1.07401 Customer IDs $CM EPA Sample Number: 083 1 07-4 1b~-0i 11 This sample was received bl' our lab: Coutplianoe File Number: 107-245-4105 Sample )description: Swab sample into a $oz.glass container of tho window close La north Codplisoee Fie Name: Naimandy Shores Golf et~t ~~ of the house, located at the east side of Course the house, cop right gla4s of tht window. Date Sample Taken: 08x31/07 Submit Datr: ~8~/45/07 ~"he attached reFvrt is for the sample referenced above. The sample was analyzed usi»g standard FDAt"S testing procedures acid quality analysis protocol. Instrument calibration and quality ctiantrol are within acceptable limits of pr+ecisiorr artd accuracy. ' A close review by our Quality Assurance .£)epartment cert~es that our.strlct quality assurance standards were observed. This cover sheet is an integral part of the artalytieul report that, follows. FesticYde Laboratory REPO~t~ Off' ~N,A-LYSIS To: Bureau of Compliance Monitoring 31 Z5 Conner Souievar+d, BId.8 . Tallahassee, FI.32399-1650 EPA Ssm pie No: 0831071t 105-0 I I 1 Sample Maui=: SWAN Report Date: 9/148007 Date Received: 09/05/07 Date Collected: 08/31/07 Sample Description: Swab sample into a Soz.glass container of the window close to north east comer of thG boost, locatad at the east side of tht boost, top right glass of the window. This sample was analyzed by standard Pesticide Laboratory, FbACS testing procodures. ,411 results were validated against standard QA procedures. Anal~rtical Results N Ana is_.y,_~__ ~......^.~_Resu~t __ ~ Analysis Ueit ---- , Aaal~te MDL _~.. Fluatifo~P-b~---• • ---•- Notdetocted ug_ _.. __... ~. ... Pluazifop-p_butyi _ ._ - _ C~mtments• See attached page for report qualifier definitions if applicable u ''' ~ u: P.A_ Lutes, Division of ASS Florida Departmart of Agriculture and Consumer Services (850) 488-9375 State of Fiori~l~ department of Aglriculture & Consumer Services '~'niinh~ssee, Florida Charles H. Bronson Commissioner PESTICIt?E ANALYSIS REPORT Report Dane: A114l20Q7 L~alroratary sample lD: PL47403 Customer 1D; BCIVI EPA Sample Number: 483147-4145-0113 Compliance File Number: 147-345-4105 Compliance File Name: Normand}- Shores Golf Course This sample was received by our lab: Sample Deacriptitrn: S«-ab samgle into a doz. glass container from the n•indon' of a door close to the north east corner of the house, located at the nottlt side of the Goose (bacL• sidt) top glass Date Sample Taken: 48/31/07 Submit DaM: 49/45/07 The attached repvrt is jot the sample referenced above. The sample was analyzed using standard FDAt"S testing procedures and quality analysis prvtveol. Insrrurnent aalibrativn and quality control are within acceptable limits ofpreciston and accuracy. A close review by our Quality Assurance Department cerNfres that our strict quality assurance standards were abserv~ed. This cover sheet is pn integral part of the analytical report that follows. Pesticide Laboratory REPQRT OF ANAI,XSIS To: Bureau of Compliance Monitoring 3125 Conner i3oulevard, BId.B Tallahassee, ~'1.3Z399-1650 1uPA Sample No: 083107-0105-0113 Sample Matra; SWAB Report Date: 9/14200? Date Received: 09/05/07 Date Collected; D$/31/D7 Sample Description: Swab sample into a 8oz. glass container from the window of a door close to the north east corner of the house, located at the north Sidt of tht house (back side) top glass window. This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. All results were validated against standard QA procedures. Analytical Results Ama a Result Ana Unit Aaa MD1L alftitr r'lnaxif0 P-b 1 Not detected u Fluazif P-b 1 ~ammeiats: See attachtd pagt fpr rcpprt qualifier definitions if applicable '~+~:~. P.A. Lucas, Division of AES Florida Dcparhnent of Agriculhue and Consume= Services (850) 488-9375 • ~ „ .r Spate of Florida Department of Agriculture & Consumer Services . Tallahassee, Florida Charles H. Broeson Commissioner PESTIC~?E A1~tAI.YSIS REPORT Report Dste: 9/l4/2007 Laboratory Sa~auple ID: PL0740d Costomer m: BCM EPA Sample Namber: 083107-4105-01 i0 Compliancx File Namber: 107-245-4105 Compliance I+~le Name: Normandy Shores Galf Coarse This simple wss received by our lab: Sample Des~eriptiuu: Swab sample into a 8azglass aomauter of midle's window of the east side of the housetop glass window Date Sample Taken: 08/31/07 Sabmit Date: 04/05/07 The attached report is for the sample referenced above. The sample was analyzed using standard FDACS testiizg procedures and quality analysis protocol. Instrument calibration and quality control are within acceptable limits of precision and accuracy. A close review by our Quality Assurance Diepartment cert~eS that our strict quality assurance srurrdards were observed. This cover sheet is an integral part of the analytical report that follows. pesticide Laboratory ~~'Ot7T ~~' AI~ALYS~S To: Bureau of Compliance Monitoring - 3125 Conner Boulevard , BId.B Tallahassee, FI.32394-1650 EFA Sample No: 083107-4105-0110 Ss®ple Matrix: SWAB Report Date: 9/14!2007 DatE Received: 09/OS/07 Date Calleeted: 08/31/07 Sample Ibescriptiua: Swab sample into a 8oz.glass container ofmidle's window of the east side of the housetop glass window This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures, Ail results wire validated a;~inst standard QA procedures. A~~~Yt~CU~ R85U~tS Ana a _.., ,.m~- •- __- • -----.--! Resslt ~Mal~~ Glypitosate & AMPA in Swab by~ _ - -° .,_ .. -- -dug -- -- -C/Flaores _ AminometFtyl phos~honic acid-••- ----- _ .._. Not detected _.G~Bhosate _ ... _ Not detected -~---- ----~ Comments: See attarc~h~cd page for report qualifier definitions if applicable F.A_ Lucas, division of AES Florida DBpartrnent of Agriculture and Consumer Services (850) 488-9375 ..` ~ ; State of Florida - Department of Agriculture & Consumer services Tallahassee, ~`lorida Charles H. Bronson Commissioner PESTiCIU)E ANALYSIS R,EI'QRT Report ,Date: 9114!2007 laboratory Sample m: PL07394 Customer ID: 13CM EPA Sample Namber: 083107-4105-0104 This aampte was received by our lab: Compliance Flle Number: 107-245-4105 Sample De~cripdou: Swab sample into a 8oz. container of the window close to the southeast Compliance File Name: Normandy Shores Golf ~~ of the house, located at the east side of the Course house„ top left glass window. Date Sample Taken: 08/31/07 Submit Date: 09/05/07 The atTached report is for the sample referenced above. The sample was analyzed usinl; standard FDACS testing proced:aes Quad quality analysis protocol. Ltstrument calibration and quality control are within acceptable limits of precision and accuracy. A close review by our Quality Assurance Department certifies that our strict quality assurance standards were observed. This cover sheet is an integral part of the analytical report that follows. Pesticide Laboratory REPORT OF A.NA.I.T-TSIS To: Bureau of Compliance Monitoring 3125 Conner Boulevard , BId.8 Tallahassee, Fl. 32399-1650 E1PA Sample No: 083107105-0I09 Sample Matrix: SWAB Report Date: 9/1412007 Date Received: 09/OS/p7 Date Collected: 08/31/07 Sample Description: Swab sample into a $az container ofthe window close to the southeast corneraf the house, located at the east side of the house, top left glass window. This sample was analyzed by standard PesuGide ~,aboratory, FDACS testing procedures. All results were validated against standard QA procedures. Analytical Results ,,.!~~~ .-.._. _ .. _. ...._ :Result ' AaalUrit -_ _! Ana a MDL alit'ier I Ftuatitop-P-~1 _.. .-...~ Notdetecled up-------- •- -- ~ ... .r. ~'luazifg>-P=bury - -------- Comments; See attached page for report queli~itr definitions if applicable -----•.. P.A- Lucas, pivisivn of AF.S Florida department pf Agriculture and Consumer Services (850) 488-4375 State of Florida - Department of Agriculture & Consumer Services "Cal~ahassee, Florida Charles H_ t3ronson Commissioner PESTICIDE ANAY,,;YSIS it~PURT Report ID$te: 9/14!2007 Laboratory Sample ID: Pi-07398 Costamer IID: BCM EFA Sample Namber: 083t07-4105-010$ 'I'bis sample was received by our lab: Compliance File tvniaber: 107-245~#lOS Sample Descriptio®; Swab sample into a 8 ozglass ooutrtiner of the windows close to lYV-r Comptfaace l~le Name: Normandy Shores Golf corner ofthe house at the west side ofthe House, left Course glass of the window. Date Sample Taken: 0$!31/07 Sabmit Date: 09/OS/07 ate attached report is for the sample referenced above. 7'3~e sample was analysed using standard FDACS testing procedures and quality analysis protocol. Instrument calibration acrd quality control are within acreplable limits of pt+ecision and accuracy. }( close renew by our ~JualityAssurance laepartment certifies that our strict quality assurance standards were observed. This cover sheet is art integral part v f the analytical report that fpllo~~s. Festicide Laboratory REPORT OF ANALYSIS To: Bureau of Compliance Monitoring 3125 Conner Boulevard , BId.8 Tallahassee, Ei. 32399-1550 EPA Sample No: 08310'I-4105.4108 Sample Matrt::SWAB Report Date: 9/1412007 bate Received: 09/05/07 bate Collected: 0813 t /07 Sample beseription~: Swab sample into $ 8 oz.gtass container of the windows close to NW comer of the house at the west side of the house, left glass of the window. . 'lltis sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. All results were validated against standard QA procedtu~es. Analytical Results Glypiosate do ,MIPA lea swat- by ----------; u~ -------~--~ .~~ ------------ _ ~-- [.C/F7nores AminomcthYl~hos _ic acid ... Not detected _Gly_phosate - - ----- ... --------._._-----. ...., _ . _-- .-, -, , Not detected -. - Colin pl~iDtS: See adfsehed page for rtport qualifier definitions if applioablc ~~ rwc ~ - P.A. Lucas, Division of AES F Iorida Departrraent of Agriculture and Consumer Servicxs (850) 488-9375 ~~ - .. ,. ~ State of Florida Department of Agriculture & Consumer Services Tallahassee, Flarid~ Charles H. B~onsan Commissioner PESTICIDE AN.ALYSYS REPORT Deport Date: 9/i4/2b07 ~boratory Sample ID: PL07397 Customer ID: BCM EPA Sample Number: 083107-4105-0107 Compliance File Namber: I07-245-4105 Compliance Idle Name: Normandy Shores Golf Course This sample was received 6y our Ixb: Sample Yl-eaeriptioa: Swab sasrple of the idtchen window located at the west side of the house,top window's glass. Date Sample TAken: 013131/07 3ebmlt Date: 09/05/07 The attached report is for the sample referenced above. The ,sample was analyzed using standard FDACS testing procedures and qualify analysis protocol instrument calibration and quality control are within acceptable limits ofprecision and accuracy. A aluse review by our,Quality Assurance Department certi}ies that our strict quality assurance standards were observed This cover sheet is an integral part of the analytical report that, folloKS. Pesticide i.aboratory REPORT OF ANALYSIS To: Bureau of Compliance Monitoring 3125 Conner Boulevard , Bld.8 Tallahassee, Fl. 32399-1650 EPA Sample No: 083107~l105-0107 Sample Matri::SWAB Report Datc: 9/1412007 bate Received: 09/05/07 Date Collected: 08/31/07 Sample Description: Swab sample of the kitchen window located at the west side of the housetop window's glass. This sample was analyzed by standard Pesticide Labaatory, FDACS testing procedures. All results were validated against standard QA procedures. Analytical Results ~~ Anatyte -__ .•.Resak Analysis_17ait . ! Anayte_MDL•_ 'Qualifier ... _Floaaifap-P-b°tyl ... . .... .. . . .Nat detected --°~----•- - --- ---- Fluazifop-P-b 1 ._..._--~------. -- ---•----- COW d]@>It3: See attached page for report qualifier definitions if applicable .~ ::I ~~a. P.A. Lucas, Division of AES Florida Department of Agriculture and Consumer Services ($50) 48$-9375 ~~- ,; r~.. State of Florida Department of Agriculture & Consumer Services Tallahassee, Florida Charles H. Bronson Commissioner PESTICIDE ANALYSIS REPt.~ItT Report Date: 9/I4/2007 Traboratory Sample CD: p1.07396 t"ustomer tI?: DC1M EPA Sample Number: 083107-4105-0106 Compliance Fik Number: 107-245-4105 Compliance File Nsme: Normandy Shores Gvlf Course This sample was received by our lab: Sample Description: Swab sample of a window located in front of the house close to the south west corner of the bousttop left glass of window. Date Sample Takeo: 08/31/07 Submit Axle: 09/05/07 The attached report is for the sample referenced above, The son:ale was analyzed using standard FDAC,S testing procedures and quality analysis protocol_ ,Instrument calibration and quality control are within acceptable limits of precision and accuracy. A close review by vur Quality Assurance Department certifies that our strict qualify assurance standards were observed. This cover sheet is arr integral part of the analytical report that follows. Pesticide Laboratory REFORT aF ANALY'SYS To: Bureau of Compliance Monitoring 3125 Conner Boulevard ,1314.8 Tallahassee, Fl. 32399-1650 EPA Sample lVo: 083107-0105-0106 S#mple Maui::SWAB Report Date: 9/14~L007 Date Received: 04/05/07 Date Collected: 0813 I /D7 Sample DeBcttiption: Swab sample of a window located in front of the house close to the south west corner of the housetop left glass of window. This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. Aq results were validated against standard QA procedures. Anal~ticai Results Malyte -` ,^ ~ _- _~ Result An# Unit - Ans to MDL ~ Qoslifier _ Glyp(tosatc dr AiNPA ie Swab by J` -._ -- ; ug ------.-_ - _ .._-•__-- ~- - LGFluores --~----T ----- - -----.... -- --- ---- -- ----•---~-~--~.-..-- -- Aminomethyl~hosphonic acid - -._ _. _. , Not ddected ,-- •- - ._ -•---- _ - _-- _ _ .. G hosate Not detected Comments: See attached page for report qualifiefi definitions if applicable yC..~c" --i' ~~u~~ P.A, Lucas, Division of AES Florida Department of Agriculture 8rrtd Consumer Services (850) 488-4375 State df Florida XlepairtmeQt of ,A-gricuYfure & Consumer Services Tallahassee, Florida Charles H_ Bronson Commissioner PESTICIDE. ANALYSIS REPORT Report Date: 9/14/2007 Laboratory Sample ~: PL07395 Costomcr 1{A: BC1VI Sample Numbew 083107-4105-0105 Compliance Flk Number: 107-245-4105 Compliance Filt Name: Normandy Shores Gvlf Course This simple was received by our lab: Simple Descrlptian: Swab sample ofa window located in tPD11# ofthc housE Close to the south east corner of the house, top center glass of the wi-~pw. Ibatt Sample Taken: 08/31/07 SRbmit Date: 09/05/07 The attached report is for the sample referenced above. 7'he sample was analyzed using standard FDACS testing,procedures and quality artnlysis protocol. Instrument calibration and quality control are within acceptable limits of precision and accuraey_ A close review by our Quality Assurance Department certifies that our strict quality assurance standards were observed. This cover sheet is an integral part of the crncrlytical report that follows. Pesticide Laboratory REPORT Off' ANALYSIS To: Bureau of Compliance Monitoring 3125 Conner Boulevard , BId.B Tallahassee, FI.32399-1650 EPA Sample No: 083 t07-4105-0105 Sample 1V~atrix: SWAB Report Date: 9~14l2007 Date Received: 09/05/07 Date Collected: 08/3!/47 Sample Description: Swab sample of a window located in front of the house close to the south east comer of the house, top center glass of the window. This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. All results were validated against standard QA procedut~es. Analytical Results Analyte _---- - .': l2eEUlt Aoalygia Uoit p'lu~top-l'-but~+l _ __ _ . ,_Not detected _ _ug,_+ ._ ~~_T_ . - _. Fluati P_butyl _ _ - -_-_--_ . __.. _. _ ~OIDI Ill~lalr3: See attached page for report qualifier definitions if applicable 4.:: ~ ~~~ P.A. Lucas, Division of AES Florida Departrnent of Agriculture and Consumer Services (850) 488-9375 Analxte_MDL _i Qualifier -- , State of Florida Department of Agriculture & Coosumer Services Tallahassee, Florida Chsirlcs H. Bronson Commissioner AMENDED PESTICIDE ANALYSIS REPORT' Report Dste: 10/23/2007 Laboratory Sample ID: PL07394 Customer IU: BCM EPA Samph Number: 083107-~1~10i-O1Q4 Compliance File Number: 107-?~3S~i05 Compliance File Name: Normand}~ Shores Golf Course 'ICl~is scruple was received by our lab: Sample Description: 2lb.ol"regemtian sample into an ahtminum fail sempliag brag of a Lich~~ Tree located at front of the haase ! 1' a~~~a•- from hoase door and 26' from the street. 17gte Sample Talaeu: OS13!/07 Submit Dah: 091o5la7 ?7te attached report is for the sample referenced above. The sample was analysed using standard FDACS testing procedures and quality analysis protocol. Instrument cadihrarion and quality contra! are within acceptable limits of precision and accuracy. A close review by our duality Assurance I3epattment certifies that our strict qualit}~ assurance standards were observed. 7`hi.s coti~er sheer is an integral part of the un~lyticpl repot! shat follows. Pesticide Laboratory REPO~2'I' U~' ANALYSIS To: Bureau of Compliance Monitoring 3125 Conger Boulevard , Bld.8 Tallahasscc, FI.32399-1650 EPA Sample No: 083107-4105-0104 Sample Maui:: VEGETATION Report Date: iU/23/2007 Date Received: 09/05/07 pate Collected: 08/31/07 Simple Deat;ription: 21b,of ~vegctation sample into an alttmittum foil sampling bag of a i.ichy Tree located at front of dtt house 1 i' awAy from house boor and 26' from the street. T~ris sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. All nesuits wcro validated agarost starldara QA pr~ocedur+es. Analytical Results Aoal~te Resalt Analysis Unit Anah~te MDL t~aalifier )li'tuazifojFP~l+uh'1. ... ~ Not detecaed pph 7(x- - Fluaziti,p.p.hut~-l _ _ ~ .. . Clyphastttt dt AMPA in Vegetation by -- mgJKg -- --- LCft+'t _ _ P,minomethr~t ptu~sphcKic aciii . .. Nut detected _ (1'U . (rh~~lxtisr+te_ Nut detected O?(! - . __ . Pargaat dt Digpat in Vag M- LC/PDA --- _ _- ug/!LE _ - --~- •----- --- f)iduat F)ibramtde - _ Not Jrictited '(Il! P+trnyuatl)ichluride Not detected -~ - ~tK.i ~ ~~ Comments: See attached page far report qualifier dcfmitions if applicable Y.A. Lucas, Dn•ision of AES Florida Depbrtmcnt of Agzicultttrc arnd Cortstuner Sen~ices ($50) 4$$-4375 State of Florida Department of Agriculture & Consumer Services Talfa6assee, Florida Charles H. Bronson Commissioner AMENDED PEST'tCIDE .ANALYSIS REP(IRT Report D$be: 14/z3/Z007 lGaboratory Sample 1D; PL07393 Customer YD: )gCll~ EPA Sample Namber: 083107j1105-0103 This sample rues received by our lab: Compliance File Numl-er: 107-245-x105 Sample Description: Zlb.of ~~egetation sample into a Aluminium Foil sampling bag of A Saporilla Compliance File Name: Normand" Shores Golf Tree located in fi+oat of Mr.1:HON'S properh•. 29" Course a«~a~• from horse door cad 8' a~ti"a~" from the street. Dale Sample Taken: 08/31/07 Submit Dale: 0910/07 The attached report is for the sample referenced above. The sample was analyzed using standard FDACS resting procedures and quality analysts protocol. Instrument calibration and quality control are within acceprable limits of precesion and accuracy. ,4 Blase review by out Qualit}•Assuranee Department certi_f es that our strict quality assurance standards were observed" This cover sheet is' un integral parr of the analytical report that fo1loH:s. Pestictide L~bor~tory ~tEpU~T Off' A.NA-L'YS~S To: Bureau of Compliance Monitoring 3125 Ctxtner BoulevaM , Bld.>3 Tallahassee, FI.32399~1650 Report Aate: 1o/23noo7 EPA Sample No: 083107-4105-0103 Sample Matriii: VEGETATION Ds;te Received: 09/05/07 Pate Collected: 08/31/07 Sample Description: 21b.of vegetation sample into a Altirttinitun Foil sampling bag of A Saporiila Tree located in front of Mr.ICHON'S property,29' away fran house door and 8' away front the street. This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. Alt results were validated against standard QA procoduros. A nalytical Results ,. ,• An>altte Resalt Aosh-sis Uoit Aeghte MDL eatifier F7ag2lfup-P-bahi ~Nutdetected Y _.{,ph ]tl(~ _ -- . FlttazitilrP-hu><-I ... . GlyQbosatt & A11KPA In Vegetation by -- mg/Kg .-- ~ --- LC/PI Auiinonieth~•1 phuxph~xic acid Nut datc~ard _ . (t.3U _ C.'rltplxL+atr _ _ ...... ._ N~~t detected. - -- _IJ 3t~ . Pa<rgaat & Diyu~t io Veg h~~ LCIPDA -- t~1~F _ -- .. --' . I)iyuat I)ihronude Nut delecled ~tK? ._. !'araquatl)i<hloride NutJetretrd _ _. ?fKt .__ Comments: See attached pa8e far' report qualifier definitions if applicable •~:~_ P.A. Lucas, Di~~ision of AES Fiarida 1?epartment of Agriculture and Consumer Se~~ices {85fJj 488.9375 ~.. ,,:~~,; State of Florida Department of Agriculture & Consumer Services TaYlahassee, Florida Charles H_ Bronson Commissioner PES'TYCIDE A~TAL'YSIS REPQRT Report Date: 9/14/2007 Laboratory Sample ID: PL07342 Castomer ID: BCM EPA Sample Number: 083107105-0142 Compliance File Namber: 107-245-41QS This saptple was received by our lab: Sample Description: Analyze Free Water Sample into a 32oz glass container Compliance Yrile Name: Normandy Shores Golf Course Dste Sample Taken: 08/31/07 Sabmit Da#e: 09/05/07 The attached report is for the sample referenced above. The sample lops analyzed using standard FDACS testing procedures and quality analysts protocol. Instrume-~l calibration and quality control are within acceptable limits of precision and accuracy. A close review by our Quality Assurance Department certifies that our .strut quality assurance .standards were observed_ This cover sheet is an integral part of the analytical report that follows. Pesticide L~bar~ltory REPORT QF ,A~TA.LYSIS To: Bureau of Compliance Monitoring 3125 Conner 13oulevazd , BId.B Tallahassee, Fl. 32399-1650 EPA Sample No: 083 t07~4105-0102 Saaaple Matrix: WATER Report Date: 9/14!2007 Date Received: 09/05!07 Date Collected: 08131 /07 Sample Descriptioe: Anaiyte Ft~ee Water Sample into a 32oz. glass container '1"his sample was analyred by statadard Pesticide Laboratory, FDACS testing procedurts. All results were validated sgainsi standgrd QA procedures. Analytical Results A~ __..-._~ Rarlt ~f AuaFj~sis lluit. ._ Analyte MDL ~~uali&r ' ~ ~_ F'luaxifop•P-bot~l - ------ _--- Not deter-led 'wpb __ -~-._... _--.-- 8.0 = . F lua2ifo~-P-butyl ... - - - -- - - -. Glyp6osato ~ AMPA io Water by --- mglL --- ._ LC/Fluores _ _ Amin~l ~hosphonic acid Not detected 0.05_ _Glyphosate ~ Not detecttd 0.05 Comments: See attached page for report qualifies definitions if applicable P.A. Lugs, Division of AES Florida Department of Agricutturt and Consumer Services (550) 488-9375 ~~ .: ~ . State of Florida Department of Agriculture & Consumer Services Tallahassee, Florida Char{es H. Bronson Commissioner PESTICIDE ANALYSYS REPORT Report Date: 9/14/2007 Laboratory Sample, ID: PL07391 Customer ID: $CM EFA Sample Number. 083 i 07~ 105-0101 Compliance lH"ile Number: 107-245105 Compliance Fjle Name: Normandy Shores Golf Course Ibis sample was receirved by our lab: Samipfe Descriptiaq: Swab Sample Equipment 131xnk into a 8oz~81ass container Date Sample Taken: 08/31/07 Submk Date: 04/05/07 The attached report is for the .sample referenced abaY~e. Tire sample was analyzed using standard FDACS testing procedures and quality analysis proeocal. Instrument calibration and quality control pre within acceptable limits of precision and accuracy. A close review by our Quality Assurance Department certifres that our strict quality assurance standards were observed. This cover sheet is an integral part of the analytical report that follows. Pesticide • Laboratory REPORT QE .ANALYSIS To: Bureau of Compliance Monitoring 3125 Conner Boulevard, Bld.8 Tallahassee, Fl. 32399-1650 EPA Sample No: 083107-4105-0101 Sample Matrix: SWAB Report Dste: 4/14/2007 Date Received: 09/05/07 Date Collected; 08/31!07 Sample Description: Swab Sample Equipment Blank into a $oz.glass container This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. All results wore validated against standard QA procedures. A,naly#ical Results -waaryre --- - w-- -• i HeaaK _-_-~ Atlsl •,Uoit AnAt~te MDL ' QraNlftr Rlaa~fop-P-butyl - - . ------ -.--- Not detected ug-~ .. _ _ - -- _Fluaziifop-P-but~l_ -- -• -•-•-- Glypbosate & AMPA le Swab by --- ug --- _. I.C1FIaores _ Amirwmethy) phosphont'c acid _ Not detected _ _ _ _ GI hosate .-_ - .. ..__ ..... _._ . _. _ .~_p_--- .Not detected . L.U1~I111CIit3: Ste attached page for report qualifier definitions if applicable -•~ r - "~f P.A. Lucas, Division of AE$ Florida 15epartment of Agriculture and Consurr~r Services (8S0) 488-9375 - ', ,,_~:: State of Florida Department of Agriculture & Consumer Services Tallahassee, Florida Charles H. Bronson Commissioner PESTICIDE ANALYSIS REPORT Report bats: 9t 1d1t007 Laboratory Sample ID: PI,07404 Customer ID: BCM EPA Sampk Number: 083 t 07-4105-01 la Tbiis sam p1e was reeeived by our lab: Compliance Fik Number. 107-345-4105 Satmpk Description: Snub sample into a Roz. glass coatainer fi+om a sliding door of the north side Compliance Fik Name: Normund~~ Shores Golf of the house {hack side) the first Gom fast to West. Cotuse Leff glass of the sliding door. bAte Sample Taken: 08/31/07 Submit Date: 09/05/07 The attached report is for the sample referenced above. The sample was analyzed using standard FDACS tesrrng procedures and quality analysis protocol. Instrument cxrlibration and quallry control are within acceptable limits of precision and accuracy. A close review by our 4uality Assurance Department certifres that vur strict grrality assurance standards were observed. This Dover sheet is an integral part c~the analytical report that follows, Pesticide Laboratory REPO~t~' Off' A1~ALYS~S ',['o: bureau of Compiiapce Monitoring 3125 Conner Boulevard, BId.8 Tallahassee, Fl. 32399-1650 EPA Sample Nv: 083107-105-0114 Sample Matrix: SWAB Report Date: 9/14!2007 Date Received: 09/05/07 Date Cviktted: 0813 L/07 Sample ifleseriptioa: Swab sample into a 8oz. glass container from a sliding door ofthe north side of the house (back silo) the first from East to West, Left glass of the sliding door. 'This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures. All results were validated against standard QA procedures. Analytical Results Alas Resslt Ana Unit Ana MDL alitler Gtypboaate dk AMPA m Swab by LC/1F7aorea ug' -- Amin i nie acid Not detected G Not detaetod ~O~m@DtB: Sex attached page for report qualifier definitions if applicable P.A. Lecas, Division ofAES Florida Department of Agriculturt and Consumer Services (850) 488-9375 - State of Florida Department of Agriculture & Consumer Services Tallahassee, Florida Charles H. Drori.~on Commissioner AMENDED PE51'I IDE ANALYSIS REPQRT Report Date: 10/33/20(17 EPA Sample Number. 083107-4105-U 1 l 5 Compliance File Number: 107-2~5-4105 Compliance ~e Name: Normand- Shores Golf Course Laboratory Sample lD: PLO7a05 Cus#omer ID: BCM This sample was received by our lab: Sample Destriptieu: Zlb. of vegetation sargple of a ferns lceated at the south sidt of the sn'immg pool. into ao atominum foil sampling bag. pate Sample Takep: 08/31/O? Submit Da#e: Q9/05/07 The attached reporf is for tine sample referenced above. Tfte sample was analyzed using standard FDACS testing procedures anal quality analysis Protocol. Instrument crtlibration and qualiry control are within acceptable limits of precision and accuracy. A class review by our Quality Assurance Department certifies that our strict quality assurmrce standards were observed. This cover sheet is an integral part of the analytical report that follows. Pesticide ~,aboratory IMPORT OF ANALYSIS To: Bttuesu of Cortrpliance Monitoring 3123 Conner )3oulevard , Bld.8 Tallahassee, F1.32399-1b50 EPA Sample No: 083107-4105-01I5 Sample Matri>c: VEQ1yTAT1QN Report Date: 10/23/2007 Date Received: 09/05/07 Date Collected: OS/3 V07 Sampk D~seriptiion: 21b. of vegetation sample of a ferns located at the south side of the swimittg pool. into an aluminum foil saropting beg. This sample was analyzed by standard Festicidc Laboratory, PAACS testing procedures. All results were validated against standard QA procedures. ,1~nalytical Resu~~s Analyst ~ Reanlt ' Analysis Unit " Anah•te M><f)<. ratifier Flurzifag-P-l-uhi _•_ Not dctexteYl PP_t? . ~ ~ -~ 7U(t - Fh~xiti~p-P-hah4 Giypbasatc & AMPA is Vegetttian by ~_ mP~€ - --- . LC/F1 Aminumelh~ l ~xr.~tteKiC nrid Not detected tt.?(l (~l,•phusate - Nat deteclel ... U.'!G Parquet & Di u~t in V to . LClPDA ~i ~ --- _ U^_ _ ~ __ . --- --- .. _ .... .. _ . - -..._.._. X)i~]uat L)ihromide _ . No( detected .. _ _ _ , ti(K- ..Pars ail L)whloridr.. ....Not deteeted ._ 'tK) ~d~lUlttlitS: See attached page far report qualifier definitions if applic;abie P.A. Elites, Division of A8S Florida Depamnent of Agriculture and Consumer Sen~iees (850)488-9375 State p#' Florida Department of Agt~icaMture & Consumer Serrriees Tal~thassee, ~'[orida Gharlcs H. Bror-son Commissioner AMENDED i'ESTI IDE ANALYS S REPQRT Report Date: 10/1312007 Jraboratory Sample YD: PL07406 Customer ID: Bt^1K RPA Sample Number: 083107.•1105-O1 t6 Cowptiance Flie Number: 107-245~tI0S CoRnplian~ File Name: Normand~• Shores Golf Course This sample was"received.by opt lab: Sample bescriptioo~ 21h. of~-egetation sample into an aluminum foil sampling beg of azecas located oo the back Surd of the house cbse to the fence and the NW of the house. Dale Sample Takeo: 08/31/07 Sabmit Dade: 09/OS/Q7 The attached report fs for the sample referenced above. The sample was atalyzed using standard FDACS'tesring procedures and qualfty analysis protocol. Instrwnent caOffbratfon and qua!!ty control are wfthin acceptable limits of pteefsion ur~d accuracy. .1 close review by our Quality Assurance Department certifies that our strfet quality assurance standards were observed. This cover .sheet is an integral ptrrt of the analytical report that follows. Pesticide Laboratory REPQxt'T OF ANALYSIS To: Bureau of Compliance Monitoring 3125 Canner Boulevard , Bki.8 Tallahassee, Fl. 32394-1650 EPA Sample No: 083107-4105-0116 Sample Miltri;: VEGETATION Report bate: 10/23/2007 Date Received: 09/05/07 Date Collected: 08/31/U7 Semple Deat:r'iptiotn: 21b. of vegetation sample into an aluminum foil sampling bag of arecas locates! on the back yard of the house close to the fence and the NW of the house. This sample was analyzed by standard Pesticide Laboratory, FDACS testing procedures_ All rtst-Its were validated against standard QA, procedures- Ataal_ytical Results Aoahte __ ____ _ ~_ -- _ Reantt _ _ ; Anrt 'xis Uoit _ Anahte MDL Qralifier_ Flavxi[ap-P-hahi . _. _ _^.. ~---- .- N~~t dete~ctcd ~b _ _ 7W -- Fluoziti~p-P-hEm:l _ ._ _.. _ ... ... - _ . _ .... Clypbos9te & AMPA fn Yegetation by -- tngJKg --- --. GC/g1 Antinpnleth~-t ilns ix~ric xid :. r...~ __ __. _ IJ~tit tletectctit (}?(- _ . _ ..._ _.. CHrplx~sate_.__.._ . Natdetrctni. . _. .. G'U Prr~ut & Digit in Vag h}- LC/PDA _ _ _ _ ___ ug/f:~ --- -- L)i ual I)iNratnide _ - -- _ ~ t1etCeted NM --_- -(lU - F':ua~-al I)ichkiride ~~ N~~t detected - _. _ _. _ .. ..... . __ _ . 3(K- Sec attachtxl pagc for repcyri qualifier definitions if applicably v T~~ . ' --~,' P.A. Lucas, Division of AES Florida Dtpartment of Agriculture and t::onsuuner Services (850) 488-9375 ~~ State of Florid ~- Department of AgrKCUlture & Consumer Services Tallahassee, Florida Charles H. Bronson Commissioner PESTICIDE ANAt.YSIS REPURT keport bate: 9/1412(107 Laboratory Sample ID: PL07407 Customer ID: DCM EPA Sample Number: 0$3t07~105-0117 Compliance File Number: 107-2d5-4105 Compliance Fik Name: Normand. Shores Goff Coen~se This sample was received by our lab: Sample Description: Water sample .into a 32oz. glass container of the sr~~imiog pool of 14[r.Ste~~en ItOHN's properly. Date Sample Taken: 08/31/07 Submit Date: 09!05/07 The attached report rs for the sample referenced above. The sample was analyzed resrng standard F'DACS tesrtng procedures and quality analysis protocol. Instrument calibration and quality control are within acceptable li-ntts of precision and accuracy. A close review by our QualrtyEissurance Department cerhfres that our strict quality assurance standards were observed 'his cover ,cheer i.s an integral part of the analytical report that follows. Pesticide Laboratory REi?'ORT OF A.N.A-.I..xStS To: I3ureau of Compliance Monitoring 3125 Conner t3oulevard , BId.8 Tallahassee, Fl. 32399-1650 EPA Sample No: ~8310~-4105-01 t7 Sample Matriz: WAT)rR Report Date: 4/1412007 Date Received: 09/05/0") Date Caltected: 08/31/07 Sample t]escriptioo: Water sample .into a 32oz. glass container of the swiming pool of Mr.Sttven KOI~II~T's property. This sample vras analyzed by standard Pesticide l.abora#ory, FDACS testing procedures. Ali results were validated against standard QA procedures. Analytical Results Ana a ltesalt Aaa Unit Aas a MDL aGGet 1F'lnas3fo P- Not detected 8.0 Ftuazifo P-b t Gtyphesate 8c AA'[PA Iu Water by LC/t?Inorrs ttfg/l.. - Aminom 1 hos honic acid Not deucted 0.45 G Not deteded 0.05 Comments• See attached page for report qualifier definitions if appiir~le ~Y Q~ 1'.A. Lucas, Division of A>~.S Florida Department of Agriculture and Consumer Services (850) 48&9375 State of Florida Department of Agriculture & Consumer Services Tallahassee, Florida Ctrarles H. Bronson Coxnmiss,ioner A1VYEtV~D~~l PESTICIDE ANALYySIS REPORT lEtepor# Ilat~c: 10/7.3/Z007 I`atboratary Sample 1D; PL07434 Customer ID: BC11~1 EPA Sample Nrmuber: (19050?-a 105-0101 Compliance File Number. LU7-2a5-lIOS Compliance File Name: Narmand~• Shores C3olf Course This sample was receivett 6y our lab: Sample DescRptio~u: 21b of ~-egetation sample into an ahuninum foil sampling bag of grass from an island located at the nest side of Biarritz Dri<~ betn'een the south aad the north entrance of the parl:iag lot of the Bennis caart located ben~•een the sea and the Briatrifz Dri.-e. ~~-est side of Narmand_r- Shore Gvtl' Course. Date Sample Taken: 09/OS/07 Submit Dare: 09/10/07 The attached report is jot the sample referenced above. The sample was analyzed using standard FDACS testing procedures and quality analysis protocol. Instrument calibration and quality control are within acceptable limits ofprecision and accuracy A close review by our Quality Assurance Deparhnent certifies that our strict quality assurance standards were observed. This cover sheet rs an i~ttegrcrl pawt of the crnaJyticul report that follows. Pesticide L~bor~tory REPQRT QF ANALYSIS To: Bureau of Compliance MortitAt'ing 3125 Comt¢r Boatevard , Bld.8 Tallahassee, F7.32399-1650 EpA Sample No: 090507~i03-OI01 Sample Matriz: VEG1yTATlON Deport Date: 101231200? Daft Rcrcivcd: 09/10/0? pate Collected: 09/OS/07 Sample 1?taeription: 2 lb of vegetaboa sample into an alurttilttutt foil sampling bag of glass from an island located at the west side of Biarritz Drive between the south and dte north entrance of the parking bt of the tennis court located between the sea and the 8tiatritz Drive, west side of Normandy Shore Golf Course. This sample vras analyzed by standard Pcslieidc Laboratory, FDACS testing proeed~ues. All results were validated against standatti QA procedta~es. !Arial'ytiGal Resul -,~ ~~ _Anahte _ Itesnlt ' Anah•sis_Unit AnahYe MbL aaliCrer Plaazifop-P-lrnhi . _ . Nut detected ; pEih 7tK~ -- ~' h~lZlfll1.'FP_I1llt~ ~----- -. . ._ . . Cq+phosate & AP'!~A in Vegetation by --- mg/iCg --- ~. LCIk7 Amittnmeth+l .w hll~'iC aCjd N~lf dCtexle~t _ (1.,~,() C*hplx~sate Notdetecttvl U't~ l~rr urt 8e Di uat rtr v A+ LC/P)<)A - u X>iyu~t C>ihrouude ... _ ..- Nit detested -- - - . .(1(I Para at Uichkxide Nut defected - --. - ?llf l ~o~nments: Sec attached page For report qualifier definition if applicab~ ~~ _ P.A. Z,ucas, Division of A.1rS Florida Department of Agrictilture arxi Consumer Services (850) 488-9375 State of Florida Department of Agriculture & Consumer Services ~'allahassee, Florida cz,aries x. B~~ri Commissioner A11~itrN~ED PESTtCtDE ANALYSYS KEPORT ir~pnrt n$te: laJl.3/wa7 . Laboratory Sample IA: PGU7435 Customer ID: IIC11~I A Samplt: Number: 1)9()507-•{ 105-0102 CompWtnce File Number: 107-2dS~3101 Compliance File Name: Norm.~nd~- Shores Golf Course This sample was received by our lab: Sample Description: 2 lb of ~~egetation sample into ao aluminum foil samp4ng bag of grass Prom the green area between the East side of Biarritz Drir~t and tfie West side of the sideaa1L. 9'feet an-a)' of the South entrance of Normandc Shores Golf Course at the Biarritz Dm~e. Date Sttaapie Takeo: 09/05/07 Submit I1af~e: 09/10/07 The attached report is for the sa-nple referenced above. The sample was analyzed using standard FDACS testing procedures and quality analysis protocol. Instrument calibration and quality control are within acceptable lrnzits ofprecision and accuracy. A close review by our Quality,Assurance Department certifies than our strict quality assurance standards were observed. This comer .sheet is an integral part of the analytical report that follows. Pesticide Laboratory REPORT OF ANALYSIS To: Bturau ofCompliance Monitoring 3125 Conner Boulevard , Bld.8 Tallahassee, F1.32399-1650 EPA Sample No: 090507-41 OS-0102 Sample Maui:: V'l;GETATIQN Report Date; 10123!2007 Date Received: 09/10/07 Date Collected: 09/05/07 Sample )Description: 2 lb of vegetation sample into an aluminum foil sampling bag of grass from the green area between the )vast side of Biarritz Drive and the West side of the sidewalk. 9'feet away of the South entrance oFNormandy Shores Golf Course at tLe Biarritz Drive. This sample was analyzed by slm~dard Pcstieidc Laboratory, FDACS testing procedures. All rrsults were validated against srandard QA procedures. Analytical Results Ansh'te _ •_ . ~_Resalt ! Anahsia Unit Anshte MDL ualificr FlastZifop-P-bah~l _ .... Nor detested . PI?h 7(x) -- Fltkiziti~lrF'-huh•f. . _ ..... . _ _ _ ... _ .. _ . . _ ... Glyphosate ~ A9'CPA !n Vcgetatloa by --- mg/Kg .-_ ___ LC1F1 ._..._._..,,...,.._._ _ . _ . _ .._. _ T ,~ ~ Aaiinonieth~•1 ~~.e~lt~xic acid - - _ - - Nut detected U.'U C.*I~~pltc~w~IC __ Nut detectctii __ - p?p Pargaat & fbiquat io Vag 6}. LC/PbA -- u~1f~~ - --- f>i~ru~t Dihrunudc _ . _ Not ~tected _ _ _ _ _ . - _ _(N) Parayiiat Uicl~lariJe _ Nat detecaed _ -'W. _ __ . __ _. ._ _. ..~ ~Dt>tlfl118ft11'3: See attached page far repnd qualifier definitions if applicable ~~ '~/ ~`-~csr. j.. ---r..ea.:: P.A. LUCas, Division of AES Florida Department of Agriculture and Consumer Services (t;SA) A$$-9375 State ol• Florida Departmeint of Agriculture & Consumer Services Tallahassee, Florida Charles H. Branson Commessioner AMENDED PESTICIDE ANAI,XSIS I~POIt'I' Report bate: 14/23/2p07 1Lnboratory Sample 1(D: PL07436 Customer lA: l;Ci-~ EPA Sample Number: 090507.4l05~0103 Compliance Fik Namber: 107-2d5-~ 1 OS Compliance 1~k Name: Normtuad~~ Shores Gulf Cotuse This sample was received by oar lab: Sample Description: 2 !b of regetatian sample inW an alumiuam foil sampling bag of grnss ftpm ld3' an-ac of the Fast side of Biarritz l7ri~•e. 5' an•a~• of West side of the concrete surface and 7' a~~•a}• of the North side of a padmqunted tEansformer. riaa sample Tak~ea: 09/05/07 Submit bate: o9nt1ro7 The attached report is for the sample referenced above- The sample was analyzed using standard FDAC.S resting procedures and ~tralfty analysts protocol. Instrument calibration and quality ca~ntro! are within acceptable limits ofprecision and accuracy. A close review by our Quality ASSrmgnce Department Certr~es chat our strict quality assurance standards were observec~i This cover sheet is an rrrlegral part of the analytical report that follows. Pesticide Laboratory REPORT OF ANALYSIS To: Bureau of Compliance Monitoring 3125 Cormtr Boulevard , B1d.8 xallahassee, ~'!. 37399-1650 ir~A Saenpte Ko: 0905Q7'-4105-0103 Sample 14Cautti:: V'~GETATIQN Report Date: 10/23/2007 Date R~e+ceived: 09/10/07 Date Collected: 09/05/07 Sample Descnpdo,n: 2 lb of vegetation sample into tilt alumintuta foil sampling bag of grass from la3' away of the bast side of 13iarria Drive, S' away of West side of the conergte surface and 7' away of the North side of a parimotmted transforrrter. This sample was affilyzed by standard Pesticide LaUbratory, FDACS ICStSrtg procedures. All results were validated against standard QA procedw~s. Analytical Results Anahte , ~_~_ w _ _, __ _, ~~Rssttlt_____._; Anxhxix Unit __.,_ AhAh'te 11~L ' Qu~tifier Ftunaifa~--P-buh1 ~ Not dr(rotrd ---- rpb _ _ _ - 7{Mi Fh4~ziti~ P_huh_t . -- GtypbosaGe & AMPA iu vegetation by - . . mg/Kg - - LC/[rt _Amux~nteUn~llyl3c>,3ptx~ric acid -- . _ ..~ ~;_..__. _ . U _~U FF.1.) GI}~phosrte , ._ ... 5~ ... t-?U FF.1 Pur oat & Dr ant w V b~ LC/PDA .... 9. ~. ~ --- _u},:/F~g ... .~. _ i)iyuar pibro,nidc . N~~t derect~l ?(Ki Parayuat ~)iehlaride Nnt detrcleil _ _ 2(K.r Comments: SeC attached page for report qualifier definitions if applicable _y P.A. Lucas, Division of AES Florida Department of Agriculture and Consumer Sexvices (850) 4RR-9375 ::`~• : State of Florida Department of Agriculture & Consumer Services Tallahassee, Florida Charles H. Branson Commissioner AMENDED PESTICIDE ANALYSIS REPORT Report Date: X0/23/?007 Laboratory Sample ID: PL0743? Customer ID: BCM EPA Sample Number: (190507--1105-0104 Compliance File Nwnbet: 107-245105 Compliance File Name: Normund}• Shores Golf Course This sample was received by our lab: SAUtpk Desretiption: 21b of ~•egetatioa into an aluminum foil sampling bag of grass fropp 13' an~a}~ of the GVest side of a tcmporan• blacl--building fend. 12' aaat• of the East side of a concrete surface and 51' aea}• of the propert}• fence of the properties located at the South side of Normand~• Shoats Golf Course. Date Sample Taken: 00/05/07 Submit Date: 09!10/07 7~e attached report is. for the sample referenced above. The sample was analyzed using standard FDACS testing procedures and quality analysis protocol. ,fitstrumenr cutibration and quality covttro! are within acceptable limits of precision and accuracy. A close review by our Quality Assurance Department certifies that our strict quality assurance standards were observed. This cover sheet i.s an integral part of the analytical report shat fellows. Pesticide Laboratory REP~R.T 4F ANAY..YSxS To: Bureau of Compliance Monitoring 31 ZS Conner Boulevard , Bid.B Tallab,assee, F1.32399-1650 EPA Sample No: 094507-4105-0104 Sample Matrix: Vl3GBTATION Report Date: 10/23/2007 Aate Received: 09!10/07 D$te Collected: 09/05/07 Sample Description: Z lb of vegetation into alt alttminurtw foil sampling beg of grass from 13' away of the West side of a temporary black-building fence, 12' Away of the Fast side of a concrete surface and 51' away of the property fence of the properties located at the Sotrtit tads of Normandy Shores Goff Cotuse, This sample was analyzed try standard pesticide Laboratory, FDACS testing pt+oCedtmes. All testilts were validated against startdffid QA procedrrr+es. Analytical Results Aoahie ~ Reaolt Anah'xis Unlt Aoahte_MUL ~lifier FlaazitFo P-bnhi Not detected Fltfirziti~~P-bun' l _ Glyphosate & AMPA It- Vegetation by --. mg/tCg --- .•• LC/F'1 Aminonttth._L~+hc~plkx'fc ~cld_ _ Nut detc~ted . . tl.~U N _('Tlr~txisate.._ ... 1 ~ ...._.... _ ... .. ... _ _ _..._ ..._. _ .. . U,?U ... _ .: _FF.I _ . _ Par aq at & piquet io V be LC/PDA -- u ~ -- -- Uiyu;~t Uitxc~nridc . . N„t detrctC~i 't)ft _ .. . Parayuat DichkxiJe Nut Jetec:ted ... .... _ _ _ _ .. _ . _... _ _ . _ . ?tNt Comments; Soe attactx,d pagr Car report qualifier definitions if appli~:ahlc P.A. Lucas, Division of AES Florida Departrncnt oC Agriculnue arrd Consumer Services (850) 48R-9375 Reporfiing Qualifier Definitions A ADL is above Level of detection sis orned hood Laborato 8 ~L)L is below level of detection an sis ormed Food Laborat C D Tht once was confirmed dual column chromato h . . Semple analysis could not be performed due to irrsufl;cient sample size. Ir Fstimatod valnc- oorsxrrtratiarag as fall outside the calibration ran c. F G Value is the menu of turn or more deterninations. The a was confirmed Gas Chro /Nags S GC/MS . H Sam k anal zed out of hold time. L The presence of this amalyte was unable to be conFrmed by Mass SpeCtroscoPY due to instrtunent sensitivi limitations. J Value is >MDL but L' for information on K Sam !e not red due to sam le matrix interferences. L The was confirmed Li t;ltro /Mass S C/MS . M Aaarra#e quantitation was mat possible due to matrix inta'feTencxs. N There are indications of the of this at below tlx lowest method standard level. O Sam Ie bottle broken in I 'or to lotion of sis. F Sam le out of hold tune. Q The laborawry was unable to accurately quantitate the amount present in the sample due to the limited atnOllnt Of Available. R 'L'be data are unusable (analyze may or may not be present). Resamplimg and reanalysis is for verification. S Tire 1 does cot have the 'ate anal 'anent for this T The analysis was 5ront an unptesaved or nnproperly preserved sample. Sample iobe$rtty may be mired. Y The 1 does not have validated methodol for this sis. W The analyze was positively ideatifiod; the auecisted numerical value is the approximate ecnaatratian of the m the le. X Y S e arrived beckon recei - unable to is was uaabk to be eted due to method difficulties tbat exhausted the le. Z is not ormed Pesticide AA The analyze was not detected, however some or all ofthe quality control data for the analyze were outside QA criteria, and the presence or abtxnce of the analytc cannot definitively be determittcd from the data X13 le ' be le received 1 into C7C be nom doe pp chain of doauntrrtation defici DD be le t+eaeivad at above l0 C. L?I? The was confirmed I-IPLC-PDA S Fl: The wan dexerurined EIP1:G with Rluoresoee-ce detection. t7G Comlirnratidn Methado not available. Other Lab Report 1]tfimitions MDL The method detection limit (MrSL) is defined as "the minimum eoncentration of a substance that eeo be measured and reported with 99% confidence that the a~lyte concentration is than zero." 40 CFR 136A odic B PQL The practical quantitation limit (PQL) is defined as "the lowest concentration of am analyte that can be reliably measured within speei6ed Limits of precision and accuracy during routint 1 conditions." 50 FR 46966 The L = 3 x MDL value_ NA Not -The ( did not conduct a test for this NI7 Not Detected st or above the MDL for sample results reported as s Concentration and Not Detected at or above the lowest method standard level for sample results reported as a weight value i.e_ swabs NR Not R tted b